ACTIVATION INFLUENCE ON CATALYTIC ACTIVITY OF MODIFIED BY METALS CATIONS SYNTHETIC ZEOLITE – MORDENITE IN TOLUENE DISPROPORTIONATION REACTION
Journal Title: Azerbaijan Chemical Journal - Year 2019, Vol 0, Issue 1
Abstract
Catalytic activities of synthetic zeolite (SiO2/Al2O3=18) – mordenite, modified by metal cations (Pd2+, Ni2+, Co2+, Nd3+, Mo3+, Zr4+, Nb5+) activated under different air stream conditions in the temperature range of 300–4200C in disproportionation reaction of toluene to benzene and xylenes were studied. It was found that synthetic zeolite – mordenite comprising Pd2+, Ni2+ and Nd3+ cations are more active than the catalysts containing Co2+, Mo3+, Zr4+, Nb5+. It has been established that in conditions under study the samples activated in dry-wet air media (by joint yield of toulene and xylene) display the most activity and selectivity
Authors and Affiliations
A. M. Aliyev, V. Sh. Aghayev, A. A. Sarijanov, R. Y. Mirzaeva, S. R. Mammedova
STRONTIUM CONTAINING SULPHONATES ON THE BASIS OF ALKYLPHENOL AS MULTIFUNCTIONAL ADDITIVES FOR LUBRICATING OILS
Based on sulphomethylated alkyl(C25–C30)phenol new modifications of sulphonate type additives-strontium hydroxyalkylbenzylsulphonate have been synthesized and studied. Developed base and medium alkaline sulphonates are c...
COMBINATION OF THE TECHNOLOGICAL REJIME OF PYROLYSIS AND THE QUALITY OF HEAVY RESIN
The dependence the yield and content of heavy resin of pyrolysis on the initial raw material of hydrocarbon has been investigated. It is shown noted that at approaching by-products which contain very valuable hydrocarbon...
THE IMPACT OF THE STRUCTURE COMPOUNDS – CHAIN TRANSFER AGENTS – ON MASS-MOLECULAR DISTRIBUTION OF POLYACRYLATES AND VISCOUS PROPERTIES OF OBTAINED POLYMERS
Radical polymerization reaction of butyl- and 2-ethylhexylacrylates with the presence of new chain transfer reagents (RAFT inifertors) were analyzed in the obtained in the basis of S-alkylarylphosphate and O-butyl-S-toly...
SUPRAMOLECULAR METALCOMPLEX CATALYTIC SYSTEMS ON THE BASE OF OIL PORPHYRINS FOR ALKENES OXIDATION
The cobalt-porphyrin complex modified by oligomer crown compounds has been obtained on the basis of oil-metalporphyrin concentrate. Synthesized complex possesses supramolecular catalytic properties. It is found that the...
SYNCHRONOUS ELECTROSYNTHESIS OF HYDROGEN PEROXIDE AND OZONE 1.Topological model
The regularities of the influence of the modification of the surface layer of tissue carbon and graphite fibrous materia on the composition, the amount of superficial functional oxygen-containing groups by different meth...