CURRENT STATE OF CATALYTIC OXIDATION OF ALKYLAROMATIC CHLOROHYDROCARBONS AND ITS DEVELOPMENT PROSPECTS
Journal Title: Azerbaijan Chemical Journal - Year 2016, Vol 0, Issue 2
Abstract
The study of synthesizing alkylaromatic chlorohydrocarbons, as well as current state of their catalytic oxidation is considered. The posibility of catalytic oxidation of chlorotoluenes in the presence of varie-tyheterogeneous catalytic systems was shown. The effects of active components, reaction time and reaction temperature on the performance of catalysts were also investigated. The appropriate optimum reaction condition for the activity and selectivity for received catalysts was designated and under that condition the highest value of conversion chlorotoluenes was determined. Meanwhile, to neutralize ecological harmful substance very important greener and safer raw materials (benzaldehydes, maleic anhydride and their chloro analogues) have been also obtained
Authors and Affiliations
A. C. Efendi, E. M. Babayev, F. A. Yunisova, B. A. Ismayılova, N. Aykan
THERMODYNAMIC INVESTIGATION OF THE PbTe–AgSbTe2 SYSTEM BY MEANS OF EMF METHOD
2PbTe–AgSbTe2 system was investigated by measuring the electromotive force of the concentration with respect to PbTe chains in the temperature range of 300–450 K. A wide region of PbTe-based solid solutions (20–100 mol%...
PHASE EQUILIBRIA ALONG THE Cu2GeSe3–Ag2GeSe3 ISOPLETH SECTION OF THE Cu2Se–Ag2Se–GeSe2 SYSTEM
DTA and XRD methods were used to study phase equilibria along the Cu2GeSe3–Ag2GeSe3 isopleth section of the Cu2Se–Ag2Se–GeSe2 system and its phase diagram was constructed. It was established that this section is non-quas...
GAS PHASE HETEROGENEOUS CATALYTIC OXIDATION OF CHLOROHYDROCARBONS
Oxidation reactions of chloroalphatic hydrocarbons studied in the presence of vanadium based oxide catalysts at the temperature range 400–6000C. Showed that their reactivity increase by the growth of the amount of carbo...
CRİSTALLİK AND MOLEKULYAR STRUKTURE OF 2,2,6,6-TETRAMETİL-4-HİDROKSİ PİPERİDİN HİDROXLORİDE
The reaction of carboxymethylation and amidation of 2,2,6,6 tetramethyl-4-hydroxy piperidine with chloracetic acid and oxalyl chloride was investigated. It was shown that instead of the expected derivatives of aminoaceti...
INVESTIGATION OF (E)-(4-HYDROXY-2-METHYLPHENYL) ACETOPHENONE OXIME AND (E)-4-HYDROXY-2-METHYLACETOPHENONE THIOSEMICARBAZONE IN SOLUTIONS BY NMR SPECTROSCOPY
The presented work is devoted to the study of dynamic processes of (E)-(4-hydroxy-2-methylphenyl) ethanone oxime and (E)-4-hydroxy-2-methylacetophenone thiosemicarbazone in solutions by NMR spectroscopy