Polymer Structures of N-[{4-(N’-Benzenesulphonicacid) AminoCarbonyl} Phenyl] Maleimide: Synthesis, Thermal and Microbial Studies
Journal Title: IOSR Journal of Applied Chemistry (IOSR-JAC) - Year 2018, Vol 11, Issue 5
Abstract
Imido-functional group contenting N-[{4-(N’-benzenesulphonicacid) amino-carbonyl} phenyl] maleimide was prepared by reacting species of maleic anhydride, 4-amino benzoic acid and 4-amino sulphanilic acid via chlorination in the presence of Diphosphoruspentaoxide (P2O5) as a catalyst in medium of N, N’-dimethyl formamide (DMF). Homopolymer, copolymers[C1BSACPMI], [C2BSACPMI], [C3BSACPMI] and terpolymers [T1BSACPMI], [T2BSACPMI] were prepared by reaction of [BSACPMI] monomer with three different of acrylates, namely acrylonitrile (AN), acrylic acid (AA) and vinyl acetate (VA) in presence of tetrahydrofurane (THF) polar organic solvent. The structures of these compounds were confirmedby FT-IR, 1HNMR. The weight average molecular weight (Mw), number average molecular weight (Mn) and polydisperity (Mw/Mn ratio) of polymers were determined using Gel Permeation chromatography (GPC) technique. Thermal susceptibility of all polymers were studied by Thermo Gravimetric Analysis (TGA) and DSC techniques. All polymers wereevaluatedfrom biological activities against some bacterial and fungal species.
Authors and Affiliations
Suamanjinger . , Jyoti Chaudhary, Supriya Dadhich
Keywords
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- EP ID EP414057
- DOI 10.9790/5736-1105020515.
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