Preparation of poly (N-imidazolylmaleamic acid) /nanomaterial coating films on stainless steel by electrochemical polymerization to study the anticorrosion and antibacterial action
Journal Title: IOSR Journal of Applied Chemistry (IOSR-JAC) - Year 2018, Vol 11, Issue 1
Abstract
Poly (N-Imidazolylmaleamic acid) PIM was synthesized from monomer (N-Imidazolylmaleamic acid) NIMin aqueous solution using electrochemical oxidation procedures. The polymer film was formed on Stainless steel electrodes (working electrode). Its structure has been examined by infrared, FTIR, scanning electron microscopy SEM and atomic force microscopy AFM studies indicate that the polymer was formed. Also, study the anticorrosion action of polymer film on stainless steel by electrochemical polarization method.Furthermore, enhanced the anticorrosion of polymerby nanomaterial such as (TiO2 and ZnO (bulk-nano)) by adding to monomer solution. The results obtained showed that the corrosion rate of S-steel increased with temperature increase from 293K to 323K and the values of inhibition efficiency by coating polymer increase with nanomaterial addition. Kinetic and thermodynamic of activation parameters have been calculated for the corrosion process of S-steel in acidic medium before and after polymeric coating.Furthermore were studied the effect of the preparing polymer on some strain of bacteria.
Authors and Affiliations
Khulood A. saleh, Khalil S. Khalil, Muna I. Khalaf
Keywords
Related Articles
- EP ID EP413956
- DOI 10.9790/5736-1101018389.
- Views 184
- Downloads 0
Effect of Aliphatic Diisocyanate and Aromatic Diisocyanate on the Properties of Castor Oil-Based Polyurethanes
The Study Deals The Effect Of Increasing NCO/OH Molar Ratio On The Physico-Mechanical Properties Of Isocyanate Terminated Polyurethane Prepolymer. The Prepolymer Was Prepared Using Castor Oil With Toluene-2,4-Diisocyanat...
Synthesis, Growth and characterization of L-Histidine doped Potassium dihydrogen Phosphate(LHKDP) crystals.
L-histidine doped potassium dihydrogen phosphate (LHKDP) single crystals are grown by slow evaporation technique method. The addition of amino acid to KDP influences the characterization of pure KDP crystals. There is a...
Synthesis of Allosteric Modulators of CB1 Cannabinoid Receptors
Sample compounds that could act as allosteric modulators of CB1 cannabinoid receptors were synthesized. The compounds are analogues of pre-discovered bioactive molecules that bind to the CB1 allosteric site. Allosteric m...
Effects of Near Shore Dumping of Solid Waste on Fe(Ii) /Fe(Iii) Redox Processes And Nutrients Release At The Kibarani Dumpsite, Mombasa, Kenya
Kibarani used to be a dumping site of solid waste of Mombasa on the shore of Makupa Creek. This work was aimed at evaluating the impact of this practice on the shores of the creek. Sediment samples were analysed for Fe(I...
Synthesis, Characterization and Antimicrobial Evaluation of Silver Nanoparticles Embedded Alkyd Resin Derived from Neem Seed Oil.
Silver nanoparticles were synthesized by reducing 0.1M silver benzoate salt with 2ml of neem leaf extract, in an eco-friendly, cost effective process. Silver nanoparticles were tested to have strong zones of inhibition o...