Selective Transport of Aromatic Compounds across Parchment Supported Prussian blue Membrane

Journal Title: Chemical Methodologies - Year 2018, Vol 2, Issue 0

Abstract

The study of permeation of Aromatic compounds across parchment-supported membrane treated with Prussian blue is presented. The skin layer of the metal hexacyanoferrate membrane consists of a network structure could be selectively used with defined pore size in the nanometer range to permeate molecules with different size molecules. In order to demonstrate a possible sieving of molecules, we have investigated the permeation of a variety of aromatic compounds such as aniline (An), phenol (Ph), and naphthalene (Np). For these neutral compounds, a size-selective transport was found. Size lead to a separation factor α(An/Ph) of 1.5 and α(An/Np) of 4 respectively. Finally, it is demonstrated that purely inorganic membrane of Prussian Blue (PB) can be prepared upon adsorption of ferric ion and hexacyanoferrate on porous support.

Authors and Affiliations

Ashraf El Hashani, Nura Ben Khayal, Khaled Muftah Elsherif

Keywords

Related Articles

Efficient Synthesis of β-Lactam-Containing α-Aminophosphonates Using Fumaric Acid as Mild Catalyst

A short and efficient protocol for the synthesis of novel α-aminophosphonate esters containing β-lactam moiety is described. Inexpensive and mild catalyst such as fumaric acid was used for the synthesis of α-aminophospho...

Assessment of Cr(VI) Biosorption from Aqueous Solution by Artificial Intelligence

This work investigates the efficiency of date palm fiber as a biosorbent to the removal of Cr(VI) from aqueous solution. The effect of four main factors including, the initial pH, initial Cr(VI) concentration, biosorbent...

Prediction of the structural and spectral properties and reactivity of the silicon analogs of cyclobutadiene C4-nSinH4 (n=0-4) by density functional theory computations

In recent years, it has been noted that the silicon analogs of compounds have more pharmaceutical applications because of their more lipophilicity properties. The present research paper studies the structural and spectra...

Computational Investigation of β-hydrogen Elimination in the (C2X5)2B(C2H5); X=H, F, Cl, Br Molecules

In this paper, the DFT methods were applied at the M06-2X/6–311++G(d,p) levels of theory to investigate the β-hydrogen elimination in the (C2X5)2B(C2H5); X=H, F, Cl, Br. It was attempted to show how the electronegativity...

Green Synthesis of ZnO Nanoparticles via Sol-gel Method and Investigation of Its Application in Solvent-free Synthesis of 12-Aryl-tetrahydrobenzo[α]xanthene-11-one Derivatives Under Microwave Irradiation

In this work, zinc oxide (ZnO) nanoparticles were fabricated using Arabic gum as a reducing and stabilizing agent by the novel sol-gel method without adding any surfactants. The synthesized nanoparticles were characteriz...

Download PDF file
  • EP ID EP648066
  • DOI 10.22034/chemm.2018.60860
  • Views 86
  • Downloads 0

How To Cite

Ashraf El Hashani, Nura Ben Khayal, Khaled Muftah Elsherif (2018). Selective Transport of Aromatic Compounds across Parchment Supported Prussian blue Membrane. Chemical Methodologies, 2(0), 194-203. https://www.europub.co.uk/articles/-A-648066