Hiperwalentne związki siarki, selenu i telluru. Część 2. Sulfurany 10-S-3 i 10-S-4

Journal Title: Wiadomości Chemiczne - Year 2012, Vol 66, Issue 7

Abstract

The compounds presented herein are sulfuranes 10-S-3 and 10-S-4 containing hypervalent sulfur atom. They have been known for a relatively long time. Nevertheless, they, and especially 10-S-4 species, are still of great interest due to their unique properties. The review presents recent approaches to the synthesis of these compounds, their selected structural, physical, chemical, stereochemical and electronic properties and their use as reagents and catalysts in several reaction types. The presence of structures of these types as intermediates, which explains selected reaction mechanisms, will also be shown.

Authors and Affiliations

Adrian Zając

Keywords

Related Articles

Droga pod słońce. Wczesna historia witaminy D

Two natural products are called „vitamin D”: (1) vitamin D3 which is biosynthesized in humans and animals and (2) vitamin D2 which is generated in photochemical rearrangement of a sterol of fungy – ergosterol (Fig. 1 and...

Pronukleotydy o strukturze amidofosforanów i ich wewnątrzkomórkowy mechanizm aktywacji

Nucleoside analogues have great therapeutic potential for the treatment of cancer and viral diseases. Once inside the cell, they are activated by a series of intracellular phosphorylation steps to produce 5’-triphosphate...

Aktywność biologiczna związków acetylenowych pochodzenia naturalnego

The natural acetylenic products containing at least one a carbon-carbon triple bond, are important class of compounds widely distributed in the environment. Development of spectroscopic techniques and methods for the iso...

Biokoniugaty antybiotykow jonoforowych : cele, strategie syntezy i właściwości

Polyether ionophore antibiotics (ionophores) represent a large group of naturally- occurring lipophilic compounds which are able to form complexes with the metal cations and transport them across the lipid membranes. Thi...

Alditole i anhydroalditole

Alditols belong to the group of acyclic polyols. Formally, they are obtained from the aldose or ketose by reduction of the carbonyl group. Single or double dehydratation of alditols provides the cyclic compounds named an...

Download PDF file
  • EP ID EP590187
  • DOI -
  • Views 148
  • Downloads 0

How To Cite

Adrian Zając (2012). Hiperwalentne związki siarki, selenu i telluru. Część 2. Sulfurany 10-S-3 i 10-S-4. Wiadomości Chemiczne, 66(7), 593-622. https://www.europub.co.uk/articles/-A-590187